MCQ
A compound with empirical formula AB2 has the vapour density equal to its empirical formula weight. Its molecular formula is:
  • A
    A2B2
  • B
    A2B4
  • C
    A2B3
  • D
    A2B8

Answer

B. $A _2 B_4$
Explanation :
Given,
Empirical formula $= AB _2$
Vapour density $=\frac{\text { Molecular weight }}{2}$
Molecular weight $=2 \times VD$
According to the question,
Vapour density $=$ Empirical formula weight
Molecular formula $=($ Empirical formula $) n$
$\begin{array}{l}
n=\frac{\text { Molecular weight }}{\text { Empirical formula weight }} \\
=\frac{2 \times VD}{VD} \\
n=2
\end{array}$
So, molecular formula $=\left( AB _2\right)_2$
$=A_2 B_4$
Hence, the molecular formula is $A _2 B_4$.

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