Question
A crystalline solid has a cubic structure in which tungsten $(W)$ atoms are located at cube corners of the unit cell, oxygen atoms at the cube edges and sodium atom at the centre. What is the molecular formula of the compound?

Answer

Number of W atoms per unit cell $= 8($at the corners$) \times\frac{1}{8}=1$
Number of O atoms per unit cell $= 12($at the edge centres$) \times\frac{1}{4}=3$
Number of sodium atoms per unit cell $= 1($at the cube centre$) × 1 = 1,$
Nence, the formula of the compound $= NaWO_3.$

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