Question
A gaseous substance dissolves in water giving a pale blue solution which decolourises $\mathrm{KMnO}_4$ and oxides KI to $\mathrm{I}_2$. Identify the gaseous substance.

Answer

$\mathrm{N}_2 \mathrm{O}_3$ is gaseous substance.
$\mathrm{N}_2 \mathrm{O}_3+\mathrm{H}_2 \mathrm{O} \longrightarrow 2 \mathrm{HNO}_2$ (pale blue solution)
It decolouries $\mathrm{KM}_{\mathrm{n}} \mathrm{O}_4$ oxidises $\mathrm{HNO}_2$ to $\mathrm{HNO}_3$ and gets reduced to $\mathrm{M}_{\mathrm{n}^{2+}}$ which is colourless.
$\mathrm{HNO}_2$ oxidises $\mathrm{KI}$ to $\mathrm{I}_2$ because $\mathrm{I}^{-}$is good reducing agent.

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