MCQ
A solution of acetone in ethanol
- Aobeys Raoult's law
- Bshows a negative deviation from Raoult's law
- ✓shows a positive deviation from Raoult's law
- Dbehaves like a near ideal solution.
✓
Answer
Correct option: C.
shows a positive deviation from Raoult's law
c
A solution of acetone in ethanol shows a positive deviation from Raoults' law due to miscibility of these two liquids with difference of polarity and length of hydrocarbon chain.
A solution of acetone in ethanol shows a positive deviation from Raoults' law due to miscibility of these two liquids with difference of polarity and length of hydrocarbon chain.
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$\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,HOC{H_2}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|
\end{array}} \\
{{H_2}C = CH - C{H_2} - C{H_2} - C - OH} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2} - C{H_3}}
\end{array}$ $\xrightarrow[{TsOH}]{{\begin{array}{*{20}{c}}
O \\
{||} \\
{C{H_3} - C - C{H_3}}
\end{array}}}(A)$ $\xrightarrow[{{{(C{H_3})}_2}S}]{{{O_3}}}(B) + HCHO$ Product $(B)$ is
→{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,HOC{H_2}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|
\end{array}} \\
{{H_2}C = CH - C{H_2} - C{H_2} - C - OH} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2} - C{H_3}}
\end{array}$ $\xrightarrow[{TsOH}]{{\begin{array}{*{20}{c}}
O \\
{||} \\
{C{H_3} - C - C{H_3}}
\end{array}}}(A)$ $\xrightarrow[{{{(C{H_3})}_2}S}]{{{O_3}}}(B) + HCHO$ Product $(B)$ is