MCQ
According to molecular orbital theory, the number of unpaired electron(s) in $\mathrm{O}_{2}^{2-}$ is :
  • A
    $1$
  • $0$
  • C
    $2$
  • D
    $3$

Answer

Correct option: B.
$0$
b
Molecular orbital configuration of $\mathrm{O}_{2}^{2-}$ is

$\sigma_{1 \mathrm{~s}}^{2} \sigma_{1 \mathrm{~s}}^{*} \sigma_{2 \mathrm{~s}}^{2} \sigma_{2 \mathrm{~s}}^{*_{2}}\left(\pi 2 \mathrm{p}_{\mathrm{x}}^{2}=\pi 2 \mathrm{p}_{\mathrm{y}}^{2}\right)\left(\pi_{2 \mathrm{px}}^{*}=\pi_{2 \mathrm{py}}^{*}\right)$

Zero unpaired electron

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