- ✓$HCHO$
- B$C{H_3}C{H_2}CHO$
- C$C{H_3}CHO$
- D$C{H_3}COC{H_3}$
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$\mathrm{M}(\mathrm{s}) \mid \mathrm{M}^{+}$(aq; $0.05$ molar) || $\mathrm{M}^{+}(\mathrm{aq}), 1$ molar) $\mid \mathrm{M}(\mathrm{s})$
For the above electrolytic cell the magnitude of the cell potential $\left|E_{\text {cell }}\right|=70 \mathrm{mV}$.
$1.$ For the above cell
$(A)$ $\mathrm{E}_{\text {cell }}<0 ; \Delta \mathrm{G}>0$ $(B)$ $\mathrm{E}_{\text {cell }}>0 ; \Delta \mathrm{G}<0$
$(C)$ $\mathrm{E}_{\text {cell }}<0 ; \Delta \mathrm{G}^{\circ}>0$ $(D)$ $\mathrm{E}_{\text {cell }}>0 ; \Delta \mathrm{G}^{\circ}>0$
$2.$ If the $0.05$ molar solution of $\mathrm{M}^{+}$is replaced by $0.0025$ molar $\mathrm{M}^{+}$solution, then the magnitude of the cell potential would be
$(A)$ $35 \mathrm{mV}$ $(B)$ $70 \mathrm{mV}$ $(C)$ $140 \mathrm{mV}$ $(D)$ $700 \mathrm{mV}$
Give the answer question $1,2.$
| Column $I$ | Column $II$ |
| $(A)$ $\mathrm{CH}_3-\mathrm{CHBr}-\mathrm{CD}_3$ on treatment with alc. $\mathrm{KOH}$ gives $\mathrm{CH}_2=\mathrm{CH}-\mathrm{CD}_3$ as a major product. | $(P)$ $E1$ reaction |
| $(B)$ $\mathrm{Ph}-\mathrm{CHBr}-\mathrm{CH}_3$ reacts faster than $\mathrm{Ph}-\mathrm{CHBr}-\mathrm{CD}_3$. | $(Q)$ $E2$ reaction |
| $(C)$ $\mathrm{Ph}-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{Br}$ on treatment with $\mathrm{C}_2 \mathrm{H}_5 \mathrm{OD} / \mathrm{C}_2 \mathrm{H}_5 \mathrm{O}^{-}$ gives $\mathrm{Ph}-\mathrm{CD}=\mathrm{CH}_2$ as the major product. | $(R)$ $E1$ cb reaction |
| $(D)$ $\mathrm{PhCH}_2 \mathrm{CH}_2 \mathrm{Br}$ and $\mathrm{PhCD}_2 \mathrm{CH}_2 \mathrm{Br}$ react with same rate. | $(S)$ First order reaction |
| List I (Complex) | List $II$ (Type of isomerism) |
| $A$. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2$ | $I$. Solvate isomerism |
| $B$. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}$ | $II$. Linkage isomerism |
| $C$. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]$ | $III$. Ionization isomerism |
| $D$. $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3$ | $IV$. Coordination isomerism |
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