- AAddition of water
- BAddition of non polar solvent
- CExposure to light
- DExposure to air
Explanation:
Alkyl bromides and iodides develop colour when exposed to light. Halogens have lower bond dissociation energy. This low enthalpy means that even at normal temperature or on exposure to sunlight, they decompose and form free ions, which are coloured and hence impart colour on exposure to light.
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$(i)$ ${A_2} \to A + A$ (fast)
$(ii)$ $A + {B_2} \to AB + B$ (slow)
$(iii)$ $A + B \to $ (fast)
Statement - $I$: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow $\mathrm{S}_{\mathrm{N}} 2$ mechanism.
Statement - $II$: A secondary alkyl halide when treated with a large excess of ethanol follows $\mathrm{S}_{\mathrm{N}} 1$ mechanism.
In the the light of the above statements, choose the most appropriate from the questions given below: