MCQ
Amines are basic in nature because:
- AThey produce $OH^-$ ions when treated with water
- BThey have replaceable $H$ atoms on $N$ atoms
- ✓They have lone pair of electron on $N$ atom
- DNone of these
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Step $I\,\,:$ ${H_2}O(g)\, \to \,H(g)\, + \,OH(g)\,;$ $\Delta H = 498\,kJ\,mol^{-1}$
Step $II\,\,:$ $OH(g)\, \to \,H(g)\, + \,O(g)\,;$ $\Delta H = 428\,kJ\,mol^{-1}$
The bond enthalpy of the $O-H$ bond is....$kJ\,mol^{-1}$
$\underset{(1)}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}{{O}^{-}}}}\,\,\,\,\,\,\underset{(2)}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}{{S}^{-}}}}\,\,\,\,\underset{(3)}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,|| \\
C{{H}_{3}}C{{H}_{2}}C-{{O}^{-}} \\
\end{matrix}}}\,$