- ACH3CH2COOH
- B(CH3)2CH−COOH
- CHCOOH
- DCH3COOH
Explanation:
$\text{Acidity} \alpha \frac{1}{\text{pKa}}\alpha \frac{1}{\text{+I−effect}}$
Stronger the acid lower is the pK value. From the given acid HCOOH is the strongest acid as it do not have any +I group.
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[$A$] the physical state of $\mathrm{X}_2$ at atom temperature changes from gas to solid down the group
[$B$] decrease in $HOMO-LUMO$ gap down the group
[$C$] decrease in $\pi^*-\sigma^*$ gap down the group
[$D$] decrease in ionization energy down the group
$\begin{matrix}
O\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
||\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C-Cl-N{{H}_{3}} \\
\end{matrix}$ $\to $ Inter mediate $\to $ product