MCQ
Among the following compounds which can be dehydrated very easily is
  • $C{H_3} - C{H_2} - \mathop {\mathop {\mathop {\mathop C\limits^| }\limits_| {\mkern 1mu}  - C{H_2}}\limits^{C{H_3}\,\,\,\,\,\,\;\;\;\;} }\limits_{OH\,\,\,\,\,\;\;\;\;\;\;} {\mkern 1mu}  - C{H_3}$
  • B
    $C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-\overset{OH}{\mathop{\overset{|}{\mathop{C}}\,H}}\,-C{{H}_{3}}$
  • C
    $C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-C{{H}_{2}}-C{{H}_{2}}-OH$
  • D
    $C{H_3} - C{H_2} - \mathop {\mathop C\limits_| {\mkern 1mu} H - }\limits_{C{H_3}\,\,\,\,\;} {\mkern 1mu} C{H_2} - C{H_2} - OH$

Answer

Correct option: A.
$C{H_3} - C{H_2} - \mathop {\mathop {\mathop {\mathop C\limits^| }\limits_| {\mkern 1mu}  - C{H_2}}\limits^{C{H_3}\,\,\,\,\,\,\;\;\;\;} }\limits_{OH\,\,\,\,\,\;\;\;\;\;\;} {\mkern 1mu}  - C{H_3}$
a
$C{H_3} - C{H_2} - \mathop {\mathop {\mathop {\mathop C\limits^| }\limits_| {\mkern 1mu}  - C{H_2}}\limits^{C{H_3}\,\,\,\,\,\,\;\;\;\;} }\limits_{OH\,\,\,\,\,\;\;\;\;\;\;} {\mkern 1mu}  - C{H_3}$ $\xrightarrow{{{H^ + }}}$ $C{H_3} - C{H_2} - \mathop {\mathop {{\text{ }}C}\limits_ \oplus ^|  - C{H_2}}\limits^{C{H_{3\,\,\,\,\,\,}}\;\;\;\;{\kern 1pt} }  - C{H_3}$

The more stable carbocation is generated thus more easily it will be dehydrated.

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