MCQ
Among the following ions the $p\pi - d\pi $ overlap could be present in
- A$NO_2^ - $
- B$NO_3^ - $
- ✓$PO_4^{ - 3}$
- D$CO_3^{ - 2}$
In nitrogen and carbon, no vacant $d$-orbital is present. So, they do not form $p \pi- d \pi$ bond.
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$(I)\, (CH_3)_2P(CF_3)_3$ is non-polar and $(CH_3)_3P(CF_3)_2$ is polar molecule
$(II)\, CH_3 \widehat{P} CH_3$ bond angles are equal in $(CH_3)_3P(CF_3)_2$ molecule
$(III)\,PF_3$ will be more soluble in polar solvent than $SiF_4$