MCQ
Amongst the following element with their electronic configuration given below, which one is having highest ionisation energy ?
  • A
    $[Ne] 3s^23p^1$
  • $[Ne] 3s^23p^3$
  • C
    $[Ne] 3s^23p^2$
  • D
    $[Ar] 3d^{10}4s^24p^3$

Answer

Correct option: B.
$[Ne] 3s^23p^3$
b
The highest ionization is possessed by the element which will not want to lose its electron. Consider the options:

A) $[N e] 3 s^{2} 3 p^{1}$ - can lose the $p$ electron with relative ease.

B) $[N e] 3 s^{2} 3 p^{3}$ - since it is half filled, it is difficult to remove an electron. Hene ionization energy

will be high in this case.

C) $[N e] 3 s^{2} 3 p^{2}$ - Can lose $p$ electron with relative ease.

D) $[A r] 3 d^{10}, 4 s^{2} 4 p^{3}$ - Half filled. Difficult to remove electron.

Hence, we are left with two options, either $B$ or $D$. But in option $D$ the half filled configuration is in $4 p$ whereas it is in $3 p$ in option $B$. It is relatively easier to remove an electron from $4 p$ than $3 p .$

Hence, option $B$ is the right answer.

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