MCQ
An azeotropic solution of two liquids has boiling point lower than either when it
- A
- B
- ✓Shows positive deviation from Raoult's lawIs saturated
- DIs saturated
Also, the vapour pressure of each component is greater than that predicted from Raoult's law. Hence, the azeotropic mixture of two liquids boils at a lower temperature than either of them.
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$\begin{array}{*{20}{c}}
{C{H_3} - C - CH - C - OC{H_3}} \\
{||\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,} \\
{\,O\,\,\,\,\,\,C = O\,O\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,} \\
{C{H_3}\,\,}
\end{array}$
| Column $I$ | Column $II$ |
| $(A) \,XX '$ | $(i)$ $T-$shape |
| $(B)\,XX'_3$ | $(ii)$ Pentagonal bipyramidal |
| $(C)\,XX '_5$ | $(iii)$ Linear |
| $(D)\,XX '_7$ | $(iv)$ Square pyramidal |
| $(v)$ Tetrahedral |