MCQ
 Arrange the following compound in their correct of $pK_b$
  • A
    $III\, >\, I\, >\, II\, >\, IV$
  • $IV\, >\, II\, >\, I\, >\, III$
  • C
    $II\, >\, IV\, >\, I\, >\, III$
  • D
    $III\, >\, II\, >\, IV\, >\, I$

Answer

Correct option: B.
$IV\, >\, II\, >\, I\, >\, III$
b
$\ell_{\mathrm{P}}$ is part of Aromaticly

$\therefore $  Less basic    $\ell \mathrm{p}$ in Resonance

Reso $.$ Less         Reso $.$ More       $\therefore $  most basic

$\mathrm{IV}>\mathrm{II}>\mathrm{I}>\mathrm{III} \leftarrow pk_b$

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