MCQ
Assertion : Anhydrous $BaO_2$ is used for preparing $H_2O_2$.

Reason : Hydrated $BaO_2$ is not available.

  • A
    If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
  • B
    If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
  • If the Assertion is correct but Reason is incorrect.
  • D
    If both the Assertion and Reason are incorrect.

Answer

Correct option: C.
If the Assertion is correct but Reason is incorrect.
c
Oxygen can form $2 \mathrm{p} \pi-2 \mathrm{p} \pi$ multiple bond with itself due to its small size while sulphur cannot form multiple bond with itself as $3 \mathrm{p} \pi-3 \mathrm{p} \pi$ bond will be unstable due to large size of sulphur, but sulphur can form multiple bond with small size atom like $\mathrm{C}$ and $\mathrm{N}$.

$\text { eg. } \mathrm{S}=\mathrm{C}=\mathrm{S}$

$\mathrm{S}=\mathrm{C}=\mathrm{N} \leftrightarrow \mathrm{S}^{\odot}-\mathrm{C} \equiv{N}$

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 $\begin{array}{|l|l|} \hline \,\,List\,\,\,\,I\,\,(Compound) & \,\,List\,\,II\,\,(Oxidation\,\,state\,\,of\,\,N) \\ \hline (A)\,\,N{{O}_{2}} & (1)\,\,\,\,+\,\,5  \\ \hline (B)\,\,HNO  & (2)\,\,-\,\,3  \\ \hline (C)\,\,N{{H}_{3}} & (3)\,\,+\,\,4  \\ \hline (D)\,\,{{N}_{2}}{{O}_{5}} & (4)\,\,+\,\,1  \\ \hline \end{array}$

code :     $A \,\, B \,\,C \,\,D$      

Match List-$I$ with the List-$II$

List-$I$

Reaction

List-$II$

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Choose the correct answer from the options given below:

Dumas method involves the determination of nitrogen content in the organic compound in the form of