$(i)$ Methylamine $(ii)$ Phosgene
$(iii)$Phosphine $(iv)$ Dimethylamine

Assertion $(A):$ Gabriel phthalimide synthesis cannot be used to prepare aromatic primary amines.
Reason $(R) :$ Aryl halides do not undergo nucleophilic substitution reaction.
In the light of the above statements, choose the correct answer form the options given below.


Assertion $A$ : Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.
Reason $R$: Nitrating mixture is a strong acidic mixture.
In the light of the above statements, choose the correct answer from the options given below

$C{H_3}CN\xrightarrow{{Na + {C_2}{H_5}OH}}X\xrightarrow{{HN{O_2}}}Y\mathop {\xrightarrow{{{K_2}C{r_2}{O_7}}}}\limits_{{H_2}S{O_4}} Z$