Question
At what temperature will helium molecules have the same rms speed as that of hydrogen molecules at STP ? (Molar mass of hydrogen $=2 \mathrm{~g} / \mathrm{mol}$, molar mass of helium $=4 \mathrm{~g} / \mathrm{mol}$ )

Answer


Data : $M_{01}$ (hydrogen) $=2 \mathrm{~g} / \mathrm{mol}$
$\mathrm{M}_{02}$ (helium) $=4 \mathrm{~g} / \mathrm{mol}, \mathrm{T}_1$ (hydrogen) $=273 \mathrm{~K}$,
$v_{\text {rms }}$ (hydrogen) $=v_{2 \mathrm{rms}}$ (helium)
$v_{\text {rms }}=\sqrt{\frac{3 R T}{M_0}} \quad$ MaharashtraBoardSolutions.Guru
$\therefore v_{1 \mathrm{rms}}=\sqrt{\frac{3 R T_1}{M_{01}}}$ and $v_{2 \mathrm{rms}}=\sqrt{\frac{3 R T_2}{M_{02}}}$
Now, $v_{1 \mathrm{rms}}=v_{2 \mathrm{rms}} \quad \therefore \frac{T_1}{M_{01}}=\frac{T_2}{M_{02}}$
$
\therefore T_2=T_1 \frac{M_{02}}{M_{01}}=273 \times \frac{4}{2}=546 \mathrm{~K}
$
The temperature of helium $=546 \mathrm{~K}=273^{\circ} \mathrm{C}$

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