The p-Block Elements — Chemistry STD 11 Science — Question
Gujarat BoardEnglish MediumSTD 11 ScienceChemistryThe p-Block Elements2 Marks
Question
$\mathrm{BCl}_3$ exists but $\mathrm{BH}_3$ does not. Explain.
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Answer
In $\mathrm{BCl}_3, \mathrm{Cl}$ donates lone pair of electrons to vacant p-orbital of boron (back-bonding) making it more stable whereas in $\mathrm{BH}_3$ back-bonding is not possible, therefore, it exists as dimer. Secondly, in $\mathrm{BCl}_3$, chlorine being bigger in size cannot form bridged bonds like hydrogen in $\mathrm{B}_2 \mathrm{H}_6$.
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