MCQ
Bleaching powder and bleach solution are produced on a large scale and used in several house hold products.

The effectiveness of bleach solution is often measured by iodometry.

$1.$ $25 mL$ of household bleach solution was mixed with $30 \ mL$ of $0.50 \ M \ KI$ and $10 \ mL$ of $4 \ N$ acetic acid. In the titration of the liberated iodine, $48 \ mL$ of $0.25 \ N \ Na _2 S _2 O _3$ was used to reach the end point. The molarity of the household bleach solution is

$(A)$ $0.48 \ M$ $(B)$ $0.96 \ M$ $(C)$ $0.24 \ M$ $(D)$ $0.024 \ M$

$2.$ Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of that oxoacid is

$(A)$ $Cl _2 O$ $(B)$ $Cl _2 O _7$ $(C)$ $ClO _2$ $(D)$ $Cl _2 O _6$

Give the answer question $1$ and $2.$

  • A
    $(B,D)$
  • B
    $(B,C)$
  • C
    $(A,D)$
  • $(C,A)$

Answer

Correct option: D.
$(C,A)$
d
$1.$ $\text { milli mole of Hypo } $$ =0.25 \times 48 $

$ =2 \times \text { milli mole of } Cl _2$

milli mole of $Cl _2=\frac{0.25 \times 48}{2}=6$ milli mole

= milli mole of $Cl _2=$ milli mole of $CaOCl _2$

So, molarity $=\frac{6}{25} M =0.24 M$

$2.$ $CaOCl _2= Ca ( OCl ) Cl$

$OCl ^{-}$- Hypochlorite ion which is anion of $HOCl$ Anhydride of $HOCl = Cl _2 O$

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