Download App

STD 12 - 5. Co-ordination chemistry — JEE STD 11 Science — Question

Gujarat BoardEnglish MediumSTD 11 ScienceJEESTD 12 - 5. Co-ordination chemistry4 Marks
MCQ
Choose the correct option regarding the following complex compound which  follows $(F)$ and does not follow $(NF)$ the Sidgwick $EAN$ rule :
 
$(I)\, [(Ph_3P)_2PdCl_2PdCl_2]$         $(II)\,[NiBrCl(en)]$
$(III)\, Na_4 [Fe(CN)_5 NOS]$             $(IV)\, Cr(CO)_3(NO)_2$
 
$(I)\,-\,(II)\,-\,,(III)\,-\,(IV)$
  • A
    $NF\,-\,NF\,-\,NF\,-\,NF$
  • ✓
    $F\,-\,F\,-\,NF\,-\,F$
  • C
    $NF\,-\,NF\,-\,F\,-\,F$
  • D
    $NF\,-\,NF\,-\,F\,-\,NF$
✓

Answer

Correct option: B.
$F\,-\,F\,-\,NF\,-\,F$
b
The oxidation state of central atom $(P t)$ is calculated as

Let the oxidation state of $P t=x$, then

$(x \times 1)+3 \times(0)+(1 \times-1)+(1 \times-1)+(1 \times-1)=+1$

$x-3=+1$

$x=+4$

Thus, the $I U P A C$ name of the complex $\left[P t(N H)_{3} B r\left(N O_{2}\right) C l\right] C l$ is triamine bromidochloridonitro platinum $(IV)$ chloride as the names of the different ligands are arranged alphabetically.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Explore more

JEE STD 11 Science question papers→Gujarat Board STD 11 Science question papers→Gujarat Board question paper generator→

Similar questions

$10.30\; \mathrm{mg}$ of $\mathrm{O}_{2}$ is dissolved into a liter of sea water of density $1.03\; \mathrm{g} / \mathrm{mL}$. The concentration of $\mathrm{O}_{2}$ in $ppm$ is
→
If the bond energies of $H—H,\, Br—Br$ and $H—Br$ are $433,\, 192$ and $364\, kJ\, mol^{-1}$ respectively, $\Delta H^o$ for the reaction ${H_{2(g)}} + B{r_{2(g)}} \to 2HB{r_{(g)}}$ is.....$kJ$
→
Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is
→
A neutral atom (Atomic no. $> 1$ ) consists of
→
If the half cell reaction $A + {e^ - } \to \,{A^ - }$ has a large negative reduction potential, it follows that
→
The structure of $IF_7$ is ...... .
→
In the reaction $HCl + {H_2}O$ $\rightleftharpoons$ $ {H_3}{O^ + } + C{l^ - }$
→
The vapour density of a gas is $11.2$. The volume occupied by $11.2\, g$ of the gas at $STP$ will be.....$L$
→
The boiling point of a solution of $0.11\,gm$ of a substance in $15\,gm$ of ether was found to be ${0.1\,^o}C$ higher than that of the pure ether. The molecular weight of the substance will be $({K_b} = 2.16)$
→
$'CH_4'$ gas is obtained in :-
$(a)$ Hydrolysis of $Al_4C_3$
$(b)$ Hydrolysis of $Be_2C$
$(c)$ Hydrolysis of $Mg_2C_3$
$(d)$ Hydrolysis of $CaC_2$
→