MCQ
Cobalt $(III)$ chloride forms several octahedral complexes with ammonia. Which of the following will not give test for chloride ions with silver nitrate at $25\,^o C$ ?
  • A
    $CoCl_3 \cdot 5NH_3$
  • B
    $CoCl_3 \cdot  6NH_3$
  • $CoCl_3 \cdot  3NH_3$
  • D
    $CoCl_3 \cdot  4NH_3$

Answer

Correct option: C.
$CoCl_3 \cdot  3NH_3$
c
Octahedral complex means it contains '$6$' coordinate bond. In $\mathrm{CoCl}_{3} \cdot 3 \mathrm{NH}_{3}, \mathrm{Cl}$ cannot be outside from coordination sphere

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