MCQ
Coconut oil upon alkaline hydrolysis gives
- AGlycol
- BAlcohol
- ✓Glycerol
- DEthylene oxide
It is a saponification reaction.
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$A + B$ $\rightleftharpoons$ $C + D$ + heat
has reached equilibrium. The reaction may be made to proceed forward by
$\mathrm{I}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{I}\ \ \ \mathrm{E}^{\circ}=0.54 $
$\mathrm{Cl}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cl}^{-} \ \ \ \mathrm{E}^{\circ}=1.36 $
$\mathrm{Mn}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Mn}^{2+} \ \ \ \mathrm{E}^{\circ}=1.50 $
$\mathrm{Fe}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Fe}^{2+} \ \ \ \mathrm{E}^{\circ}=0.77 $
$\mathrm{O}_2+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_2 \mathrm{O} \ \ \ \mathrm{E}^{\circ}=1.23$
$1.$ Among the following, identify the correct statement.
$(A)$ Chloride ion is oxidized by $\mathrm{O}_2$
$(B)$ $\mathrm{Fe}^{2+}$ is oxidized by iodine
$(C)$ Iodide ion is oxidized by chlorine
$(D)$ $\mathrm{Mn}^{2+}$ is oxidized by chlorine
$2.$ While $\mathrm{Fe}^{3+}$ is stable, $\mathrm{Mn}^{3+}$ is not stable in acid solution because
$(A)$ $\mathrm{O}_2$ oxidises $\mathrm{Mn}^{2+}$ to $\mathrm{Mn}^{3+}$
$(B)$ $\mathrm{O}_2$ oxidises both $\mathrm{Mn}^{2+}$ and $\mathrm{Fe}^{2+}$ to $\mathrm{Fe}^{3+}$
$(C)$ $\mathrm{Fe}^{3+}$ oxidizes $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$
$(D)$ $\mathrm{Mn}^{3+}$ oxidises $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$
$3.$ Sodium fusion extract, obtained from aniline, on treatment with iron $(II)$ sulphate and $\mathrm{H}_2 \mathrm{SO}_4$ in presence of air gives a Prussian blue precipitate. The blue colour is due to the formation of
$(A)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(B)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$
$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$ $(D)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$
Give the answer question $1,2$ and $3.$
$\left[\Lambda_{\mathrm{m}}=\right.$ molar conductivity
$\Lambda_{\mathrm{m}}^{\circ}=$ limiting molar conductivity
$\mathrm{c}=$ molar concentration
$\mathrm{K}_{\mathrm{a}}=$ dissociation constant of $\mathrm{HX}$ ]
${C_6}{H_5} - O - C{H_2} - C{H_3}\xrightarrow{{Excess\,HI/\Delta }}\left[ X \right] + \left[ Y \right]$
$[X]$ and $[Y]$ will respectively be