MCQ
Complex species that exhibits isomerism is:
- A[Ag(NH3)2]+
- B[Co(NO2)(NH3)5]2+
- C[PtCl2(en)]
- D[CoCl(NH3)5]2+
Explanation:
None of the given complexes can exhibit either geometrical or optical isomerism. But the complex [Co(NO2)(NH3)5]2+ shows linkage isomerism as it contains nitro group which is ambidentate ligand and can be attached through either N atom or O atom.
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| $LIST-I$ $(Substances)$ | $LIST-II$ $(Element Present)$ |
| $A$. Ziegler catalyst | $I$. Rhodium |
| $B$. Blood pigment | $II$. Cobalt |
| $C$ .Wilkinson catalyst | $III$. Iron |
| $D$. Vitamin $\mathrm{B}_{12}$ | $IV$. Titanium |
Choose the correct answer from the options given below:
$2 \mathrm{H}_{2}(\mathrm{g})+2 \mathrm{NO}(\mathrm{g}) \rightarrow \mathrm{N}_{2}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$
the observed rate expression is, rate $=\mathrm{k}_{\mathrm{f}}[\mathrm{NO}]^{2}\left[\mathrm{H}_{2}\right] .$ The rate expression of the reverse reaction is