- ✓reacts slowly with $NaBr$
- Boxidises $HBr$ into $Br_2$
- Creduces $HBr$
- Ddisproportionates $HBr$
Acidic nature $ \propto EN \propto + O.S.$
For compounds of an element
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Assertion $A$: Alcohols react both as nucleophiles and electrophiles.
Reason $R$: Alcohols react with active metals such as sodium, potassium and aluminum to yield corresponding alkoxides and liberate hydrogen.
In the light of the above statements, choose the correct answer from the options given below:
$E ^0\left( Fe ^{3+} . Fe ^{2+}\right)=+0.77 V $
$E ^0\left( Fe ^{2+} . Fe \right)=-0.44 V $
$E ^{\circ}\left( Cu ^{2+} . Cu \right)=+0.34 V $
$E ^0\left( Cu ^{+} . Cu \right)=+0.52 V $
$E ^{\circ}\left( O _2( g )+4 H ^{+}+4 e ^{-} \rightarrow 2 H _2 O \right)=+1.23 V $
$E ^{\circ}\left( O _2( g )+2 H _2 O +4 e ^{-} \rightarrow 4 OH \right)=+0.40 V $
$E ^0\left( Cr ^{3+} . Cr \right)=-0.74 V $
$E ^{\circ}\left( Cr ^{2+} . Cr \right)=-0.91 V$
Match $E ^{\circ}$ of the rebox pair in List $I$ with the values given in List $II$ and select the correct answer using the code given below the lists:
| List $I$ | List $II$ |
| $P.$ $\quad E ^{\circ}\left( Fe ^{3+}, Fe \right)$ | $1.$ $\quad-0.18 V$ |
| $Q.$ $\quad E ^{\circ}\left(4 H _2 O \rightleftharpoons 4 H ^{+}+4 OH ^{-}\right)$ | $2.$ $\quad-0.4 V$ |
| $R.$ $\quad E ^{\circ}\left( Cu ^{2+}+ Cu \rightarrow 2 Cu ^{+}\right)$ | $3.$ $\quad-0.04 V$ |
| $S.$ $\quad E ^{\circ}\left( Cr ^{3+}, Cr ^{+2}\right)$ | $4.$ $\quad-0.83 V$ |
Codes: $ \quad P \quad Q \quad R \quad S $

$A +$ alkali $\rightarrow B$ (Major Product)
If $B$ is an oxoacid of phosphorus with no $P - H$ bond, then $A$ is ..... .