Question
Define and explain the term internal energy.

Answer

Internal energy : It is defined as the total energy constituting potential energy and kinetic energy of the molecules present in the system.
Explanation :
  • The internal energy of a system is a state function and thermodynamic function. It is denoted by U.
  • Its value depends on the state of a system.
  • The change in internal energy (Δ U) depends only on the initial state and the final state of the system.
    $\Delta U=U_2-U_1$
  • It is an extensive property of the system.
  • It has same unit as heat and work.
  • Total internal energy U of the system is,
    Total energy = Potential energy + Kinetic energy

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