Question
Define octet rule. Write its significance and limitations.
Significance: It helps to explain why different atoms combine with each other to form ionic compounds or covalent compounds.
Limitations of Octet rule:
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at 400K, Kp = 41. Find the value of Kp for each of the following reactions at the same temperature.
| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
$\text{PCl}_5(\text{s})\rightleftharpoons\text{PCl}_3(\text{s})+\text{Cl}_2(\text{g});$
$\Delta_\text{r}\text{H}^\text{o}=124.0\text{kJ mol}^{-1}$
$\text{BaCO}_3(\text{s})\rightleftharpoons\text{BaO(s)}+\text{CO}_2(\text{g})$
$\text{CH}_4(\text{g})+2\text{O}_2(\text{g})\rightleftharpoons\text{CO}_2(\text{g})+2\text{H}_2\text{O(g)}$