- ARed coloured sweet smelling compound
- BAcetic acid
- CEther suboxide
- ✓Ether peroxide
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| $Pb ^{2+} / Pb$ | $-0.13 V$ |
| $Ni ^{2+} / Ni$ | $-0.24 V$ |
| $Cd ^{2+} / Cd$ | $-0.40 V$ |
| $Fe ^{2+} / Fe$ | $V-0.44 V$ |
To a solution containing $0.001 M$ of $X ^{2+}$ and $0.1 M$ of $Y ^{2+}$, the metal rods $X$ and $Y$ are inserted (at $298 K$ ) and connected by a conducting wire. This resulted in dissolution of $X$. The correct combination(s) of $X$ and $Y$, respectively, is (are)
(Given: Gas constant, $R =8.314 J K ^{-1} mol ^{-1}$,
Faraday constant, $F =96500 C mol ^{-1}$ )
$(A)$ $Cd$ and $Ni$ $(B)$ $Cd$ and $Fe$ $(C)$ $Ni$ and $Pb$ $(D)$ $Ni$ and $Fe$

$H{_2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)}$ , following mechanisms were proposed
Mechanism $A$ :
$H{_2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
Mechanism $B$ :
$H_{2(g)} + ICl_{(g)} \to HCl_{(g)} + HI_{(g)}$ ; Slow
$HI_{(g)} + ICl_{(g)} \to HCl_{(g)} + I_{2(g)}$ ; Fast
Which of the above mechanism $(s)$ can be consistent with the given information about the reaction
$\xrightarrow{{NaN{H_2}}}\,A$
$2 \mathrm{~K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}+8 \mathrm{H}_{2} \mathrm{SO}_{4}+3 \mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O} \rightarrow 2 \mathrm{Cr}_{2}\left(\mathrm{SO}_{4}\right)_{3}+$
$3 \mathrm{C}_{2} \mathrm{H}_{4} \mathrm{O}_{2}+2 \mathrm{~K}_{2} \mathrm{SO}_{4}+11 \mathrm{H}_{2} \mathrm{O}$
If the rate of appearance of $\mathrm{Cr}_{2}\left(\mathrm{SO}_{4}\right)_{3}$ is $2.67 \,\mathrm{~mol}$ $\min ^{-1}$ at a particular time, the rate of disappearance of $\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}$ at the same time is ...... $\mathrm{mol}\, \mathrm{min}^{-1}$ (Nearest integer)