Question
Differentiate between retention and inversion.

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How to prepare butan-1-ol by reduction of various derivatives of acids.
When a current of 50 ampere is passed for 2 hours in the molton NaCl :
(a) How many gram of chlorine gas will be obtained at anode?
(b) What will be the volume of chlorine gas obtained at standard temperature and pressure (NTP)?
Explain the bonding in coordination compounds in terms of Werner’s postulates.
  1. What type of isomerism is shown by the complex [Co(NH3)5 (SCN)]2+?
  2. Why is [NiCl4]2- paramagnetic while [Ni(CN)4]2- is diamagnetic? (Atomic number of Ni = 28)
  3. Why are low spin tetrahedral complexes rarely observed?
Explain aldol condensation with suitable example. ### Write a short note: Aldol condensation.
Complete the following chemical equations:
  1. $\text{MnO}_{4}^{-}+\text{C}_{2}\text{O}_{4}^{2-}+\text{H}+\rightarrow$
  2. $\text{KMnO}_{4}\xrightarrow{\text{heated}}$
  3. $\text{Cr}_{2}\text{O}_{4}^{2-}+\text{H}_{2}\text{S}+\text{H}^{+}+\rightarrow$
What happens when bromine reacts with $\text{CH}_3-\text{C}\equiv\text{CH}?$ How would you justify this reaction?
Give reasons:
  1. Acetylation of aniline reduces its activation effect.
  2. CH3NH2 is more basic than C6H5NH2.
  3. Although –NH2 is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.
Match the items of column I with items of column II.
 
Column I
 
Column II
(i)
Methanol
(a)
Conversion of phenol to o-hydroxysalicylic acid
(ii)
Kolbe’s reaction
(b)
Ethyl alcohol
(iii)
Williamson’s synthesis
(c)
Conversion of phenol to salicylaldehyde
(iv)
Conversion of 2° alcohol to ketone
(d)
Wood spirit
(v)
Reimer-Tiemann reaction
(e)
Heated copper at 573K
(vi)
Fermentation
(f)
Reaction of alkyl halide with sodium alkoxide
What is meant by chelate effect?