- AIII
- BIV
- CV
- DVI
Explanation:
Electronic configuration of element with atomic number 33 is 1s22s22p63s23p64s23d104p3.
So, it is a p-block element with 3 electrons in p orbital, therefore it lies in 5 A group or 15 group.
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Statement $I :$ In 'Lassaigne's Test, when both nitrogen and sulphur are present in an organic compound, sodium thiocyanate is formed.
Statement $II :$ If both nitrogen and sulphur are present in an organic compound, then the excess of sodium used in sodium fusion will decompose the sodium thiocyanate formed to give $NaCN$ and $Na _{2} S$.
In the light of the above statements, choose the most appropriate answer from the options given below...
$3 \mathrm{PbCl}_2+2\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \rightarrow \mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2+6 \mathrm{NH}_4 \mathrm{Cl}$
If $72 \mathrm{mmol}$ of $\mathrm{PbCl}_2$ is mixed with $50 \mathrm{mmol}$ of$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4$, then amount of $\mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2$ formed is......... mmol. (nearest integer)
