Question
Expian the basic properties of amines.

Answer

SELF

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Two elements A and B form compounds having formula AB2 and AB4. When dissolved in 20 g of benzene $\left( C _6 H _6\right), 1 g$ of $AB _2$ lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K kg mol-1. Calculate atomic masses of A and B.
Draw all the isomers of: (geometrical and optical)
i. $\left[ CoCl _2( en )_2\right]^{+}$
ii. $\left[ Co \left( NH _3\right) Cl ( en )^2\right]^{2+}$
iii. $\left[ Co \left( NH _3\right)_2 Cl _2( en )\right]^{+}$
In the reaction
Q + R → Products
The time taken for 99% reaction of Q is twice the time taken for 90% reaction of R. The concentration of R varies with time as shown in the figure given alongside.

What is the overall order of the reaction? Give the units of the rate constant for the same. Write the rate expression for the above reaction.
Explain the properties and uses of methanol and ethanol.
Explain the method of preparing haloalkanes by free radical substitution of alkanes.
Classify carbohydrates and also give examples of each.
Explain Kohlrausch's law of independent migration of ions. Mention the application of Kohlrausch's law.
Explain the following reaction:
$ n-BuBr + KCN \xrightarrow{EtOH-H_2O} n-BuCN $
Giving an example for each describe the following reactions:
i. Hofmann bromamide reaction.
ii. Gattermann reaction.
iii. Coupling reaction.
Match the catalysts given in Column I with the processes given in Column II.
 
Column I (Catalyst)
 
Column II (Process)
(i)
Ni in the presence of hydrogen
(a)
Zieglar Natta catalyst
(ii)
Cu2Cl2
(b)
Contact process
(iii)
V2O5
(c)
Vegetable oil to ghee
(iv)
Finely divided iron
(d)
Sandmeyer reaction
(v)
TiCl4 + Al (CH3)3
(e)
Haber’s Process
 
 
(f)
Decomposition of KClO3