Question
Explain the alkylation process of amine compounds with example.
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Complete the following equations :
(i) $CH _3- CH _2- Cl \xrightarrow{+ A } B \xrightarrow{ C } CH _3- CH _2- NH _2+ HCOOH$
(ii) $CH _3- I \xrightarrow{+ A } B \xrightarrow{ C } CH _3- NH - CH _3$
→(i) $CH _3- CH _2- Cl \xrightarrow{+ A } B \xrightarrow{ C } CH _3- CH _2- NH _2+ HCOOH$
(ii) $CH _3- I \xrightarrow{+ A } B \xrightarrow{ C } CH _3- NH - CH _3$
Compound $'A\ ’$ with molecular formula $\ce{C_4H_9Br}$ is treated with aq. $\text{KOH}$ solution. The rate of this reaction depends upon the concentration of the compound $'A\ ’$ only. When another optically active isomer $'B’$ of this compound was treated with aq. $\text{KOH}$ solution, the rate of reaction was found to be dependent on concentration of compound and $\text{KOH}$ both.
→- Write down the structural formula of both compounds $'A\ ’$ and $'B\ ’$.
- Out of these two compounds, which one will be converted to the product with inverted configuration.
State the following:
- Raoult's law in its general form in reference to solutions.
- Henry's law about partial pressure of a gas in a mixture.
Define azeotropes. What type of azeotrope is formed by positive deviation from Raoult's law? Give an example.
Explain solubility of haloalkane.
Describe how the following conversions can be brought about (any two)?
i. Cyclohexanol to cyclohexan-1-one.
ii. Ethyl benzene to benzoic acid.
iii. Bromobenzene to benzoic acid.
i. Cyclohexanol to cyclohexan-1-one.
ii. Ethyl benzene to benzoic acid.
iii. Bromobenzene to benzoic acid.
The following is not an appropriate reaction for the preparation of tert.$-$butyl ethyl ether$:$ $\text{C}_2\text{H}_5\text{ONa}+(\text{CH}_3)_3\text{C}-\text{Cl}\rightarrow(\text{CH}_3)_3\text{C}-\text{OC}_2\text{H}_5$ What would be the major product of the given reaction?
→Explain the solubility rule “like dissolves like” in terms of intermolecular forces that exist in solutions.
Suggest a way to determine the $\wedge^\circ_\text{m}$ value of water.
→When mixed ethers in which primary or secondary alkyl group is present is treated with one mole of HI , the iodide ion $\left( I ^{-}\right)$goes to which alkyl group and why?
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