Question
Explain the close relationship between the internal structure of an atom and the emission spectrum.

Answer

Every substance (solid, liquid and gas) emits electromagnetic radiation at every temperature. This radiation contains many different wavelengths. Among these, some wave lengths are continuously distributed but their intensity varies.
This radiation arises due to the oscillations of atoms and molecules.
By heating or exciting a gas of sufficiently low density, the light emitted from it contains only a few discrete or specific wave lengths. This spectrum appear as a series of light.
Gases with sufficiently low density have more space between atoms. Hence the emitted radiation can be assumed to be due to individual atoms rather than interactions between molecules or atoms.
Each element is associated with a characteristic spectrum of radiation. For example, hydrogen always gives a set of lines with fixed relative position between the lines. Means they are at certain fixed locations.
This fact shows that there is a close relationship between the internal structure of an atom and the spectrum of radiation emitted by it.

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