Question
Explain the relationship between basicity and structure of amines.

Answer

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19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.00 C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.
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  3. Mention the two products of glycolysis.
With the help of an example explain what is meant by pseudo first order reaction.
 Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code.

 
Column I (Compound)
 
Column II (Oxidation state of Co)
a.
[Co(NCS)(NH3)5](SO3)
1.
+4
b.
[Co(NH3)4Cl2]SO4
2.
0
c.
Na4[Co(S2O3)3]
3.
+1
d.
[Co2(CO)8]
4.
+2
 
 
5.
+3

Code:

  1. A (1), B (2), C (4), D (5).
  2. A (4), B (3), C (2), D (1).
  3. A (5), B (1), C (4), D (2).
  4. A (4), B (1), C (2), D (3).
Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
A hydrocarbon 'A', (C4H8) on reaction with HCl gives a compound 'B', (C4H9Cl), which on reaction with 1 mol of NH3 gives compound 'C', (C4H11N). On reacting with NaNO2 and HCl followed by treatment with water, compound 'C' yields an optically active alcohol,'D'. Ozonolysis of 'A' gives 2 mols of acetaldehyde. Identify compounds 'A' to 'D'. Explain the reactions involved.
  1. Account for the following:
    1. Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4.
    2. Cr2+ is a strong reducing agent.
    3. Cu2+ salts are coloured while Zn2+ salts are white.
  2. Complete the following equations:
    1. $2\text{MnO}_{2} + 4\text{KOH} + \text{O}_{2} \xrightarrow{\Delta}$
    2. $\text{Cr}_{2}\text{O}^{2-}_{7}+ 14\text{H}^{+} + 6\text{I}^{-}\xrightarrow{}$
What is vapour pressure? When a non- volatile solute is dissolved in any liquid, the vapour pressure of the liquid decreases. Give reason.
Explain the limitations of valence bound theory.
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  2. Explain the following terms:
  1. Mutarotation.
  2. Avitaminosis.