Question
Explain the structure and classification of animes.

Answer

SELF

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Explain valence bond theory for coordination compounds.
Describe the reactions of carboxylic acids in which C-OH bond is broken.
Answer the following questions:
Is the variability in oxidation number of transition elements different from that of non–transition elements? Illustrate with examples.
Match the property given in Column I with the element given in Column II.
 
Column I (Property)
 
Column II (Element)
(i)
Lanthanoid which shows +4 oxidation state
(a)
Pm
(ii)
Lanthanoid which can show +2 oxidation state
(b)
Ce
(iii)
Radioactive lanthanoid
(c)
Lu
(iv)
Lanthanoid which has 4felectronic configuration in +3 oxidation state
(d)
Eu
(v)
 Lanthanoid which has 4f14 electronic configuration in +3 oxidation state
(e)
Gd
 
 
(f)
Dy
  1. Complete the following chemical equations for reactions:

i. $\text{MnO}_{4(aq)}^{-}+\text{S}_{2}\text{O}_{3(aq)}^{2-}+\text{H}_{2}\text{O}_{(l)}\rightarrow$

ii. $\text{Cr}_{2}\text{O}^{-}_{7(aq)}+\text{H}_{2}\text{S}_{(g)}+\text{H}^{+}_{(aq)}\rightarrow$

  1. Give an explanation for each of the following, observations:
  1. The gradual decrease in size (actinoid contraction) from element to element is greater among the .actinoids than that among the lanthanoids (lanthanoid contraction).
  2. The greatest number of oxidation states are exhibited by the members in the middle of a transition series.
  3. With the same d-orbital configuration (d4) Cr2+ ion is a reducing agent but Mn3+ ion is an oxidising agent.

 

  1. Define the following terms:
  1. Molarity.
  2. Molal elevation constant(Kb).
  1. A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following:
  1. $[\text{CoF}_6]^{3-}, [\text{Co(H}_2\text{O})_6]^{2+}, [\text{Co(CN)}_6]^{3-}$
  2. $[\text{FeF}_6]^{3-}, [\text{Fe(H}_2\text{O})_6]^{2+}, [\text{Fe(CN})_6]^{4-}$
Match the terms given in Column I with expressions given in Column II.
  Column I
  Column II
i. Mass percentage
a. $\frac{\text{Number of moles of the solute component}}{\text{Volume of solution in litres}}$
ii. Volume percentage
b. $\frac{\text{Number of moles of a component}}{\text{Total number of moles of all the components}}$
iii. Mole fraction
c. $\frac{\text{Volume of the solute component in solution}}{\text{Total volume of solution}}\times100$
iv. Molality
d. $\frac{\text{Mass of the solute component in solution}}{\text{Total mass of the solution}}\times100$
v. Molarity
e. $\frac{\text{Number of moles of the solute components}}{\text{Mass of solvent in kilograms}}$
What is vapour pressure? When a non- volatile solute is dissolved in any liquid, the vapour pressure of the liquid decreases. Give reason.
A voltaic cell is set up at 25°C with the following half-cells Al3+ (0.001M) and Ni2+ (0.50M). Write an equation for the reaction that occurs when the cell generates an electric current and determine the cell potential.
$(\text{Given:}\text{ E}^{\circ}_{\text{Ni}^{2+}/\text{Ni}}=-0.25\text{V,E}^{\circ}_{\text{Al}^{3+}/\text{Al}}=-1.66\text{V})$