MCQ
Fats, on alkaline hydrolysis, gives
- AOils
- ✓Soaps
- CDetergents
- DGlycol + acid
$\underset{Fat}{\mathop{\begin{matrix}
\begin{matrix}
C{{H}_{2}}OCOR \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
CHOCOR\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}OCOR \\
\end{matrix}}}\,$ $+$ $3NaOH$ $\to $ $\begin{matrix}
\begin{matrix}
C{{H}_{2}}OH\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
\,CHOH\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}OH\,\,\,\,\,\, \\
\end{matrix}$ $+$ $\underset{(Soap)}{\mathop{3RCOONa}}\,$
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$(i)$ ${C_4}{H_5}N{H_2}$ $(ii)$ $C{H_3}N{H_2}$
$(iii)$ ${(C{H_3})_2}NH$ $ (iv)$ ${(C{H_3})_3}N$
\end{array}$
Same product $(A)$ will form in both reactions $A$ is
$\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,{R_1}} \\
|
\end{array}} \\
{R - C - X} \\
| \\
{\,\,{R_2}}
\end{array}\xrightarrow{{HOH}}\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,{R_1}} \\
|
\end{array}\,\,\,\,\,} \\
{R - C - OH} \\
{|\,\,\,} \\
{{R_2}}
\end{array}$
Which substrate will give maximum racemisation?