MCQ
$[Fe(NO_2)_3Cl_3]$ and $[Fe(ONO)_3Cl_3]$ shows
- ✓linkage isomerism
- Bgeometrical isomerism
- Coptical isomerism
- Dnone of the above
✓
Answer
Correct option: A.
linkage isomerism
a
The given compound contains $-NO_2$ group which can donate electrons either from $O\,-$ or from $-\,N$. Thus , it shows linkage isomerism. Thus, the two given compounds are linkage isomers, one is nitrite $-\,O-N=O$ form and the other is nitro, (Figure) form.
The given compound contains $-NO_2$ group which can donate electrons either from $O\,-$ or from $-\,N$. Thus , it shows linkage isomerism. Thus, the two given compounds are linkage isomers, one is nitrite $-\,O-N=O$ form and the other is nitro, (Figure) form.
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