MCQ
$Fe(OH)_2$ is precipitated from $Fe(II)$ solutions as a while solid but turns dark green and then brown due to the formation of
- A$Fe(OH)_2$ and $Fe(OH)_3$
- Bonly $Fe(OH)_3$
- ✓$Fe_2O_3. (H_2O)_n$
- D$Fe_2O_3 ·2H_2O$
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$2H^+ + 2e^- + \frac{1}{2}O_2\longrightarrow H_2O_{(l)} ; $
$E^o = +1.23\, V$
$Fe^{2+} + 2e^- \longrightarrow Fe_{(s)} ;\ E^o = -0.44\,V$
| Observation | $[A]$ | $[B]$ | Rate of reaction |
| $1$ | $0.1$ | $0.1$ | $2 \times {10^{ - 3}}\,mol\,{L^{ - 1}}{\sec ^{ - 1}}$ |
| $2$ | $0.4$ | $0.1$ | $0.4 \times {10^{ - 2}}\,mol\,{L^{ - 1}}{\sec ^{ - 1}}$ |
| $3$ | $0.1$ | $0.2$ | $1.4 \times {10^{ - 2}}\,mol\,{L^{ - 1}}{\sec ^{ - 1}}$ |