- ✓the rate is independent of the temperature of the reaction
- Bthe rate is independent of the concentration of the reactants
- Cthe half life depends upon the concentration of the reactants
- Dthe rate constant has the unit $mole\, L^{-1}\, sec^{-1}$
here $k$ depends on temperature
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$\mathrm{MnO}_4^{-}+\mathrm{H}^{+}+\mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4 \rightleftharpoons \mathrm{Mn}^{2+}+\mathrm{H}_2 \mathrm{O}+\mathrm{CO}_2$
The standard reduction potentials are given as below $\left(\mathrm{E}_{\mathrm{red}}^{\circ}\right)$
$\mathrm{E}_{\mathrm{MmO}_4^{-} / \mathrm{Mm}^{2+}}^{\circ}=+1.51 \mathrm{~V}$
$\mathrm{E}_{\mathrm{CO}_2 / \mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4}^{\circ}=-0.49 \mathrm{~V}$
If the equilibrium constant of the above reaction is given as $K_{\text {eq }}=10^x$, then the value of $x=$____ (nearest integer)
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)},$
following mechanisms were proposed.
Mechanism $A\, :$
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
Mechanism $B\, :$
$H_{2(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + HI_{(g)}\, ;$ slow
$HI_{(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + I_{2(g)} \,;$ fast
Which of the above mechanism(s) can beconsistent with the given information about the reaction ?