MCQ
For an elementary reaction, $2A + B \to C + D$ the molecularity is
- A$0$
- B$1$
- C$2$
- ✓$3$
Rate $= k{[A]^2}{[B]^1}$
$\therefore $ O.R. $= 2 + 1 = 3$ and molecularity is $3[2A + B]$.
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$\mathrm{C}_6 \mathrm{H}_6(1)+\frac{15}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{CO}_2(\mathrm{~g})+3 \mathrm{H}_2 \mathrm{O}(1) \text {. }$
The standard enthalpy of combustion of $2 \mathrm{~mol}$ of benzene is - ' $x$ ' $k J$.
$\mathrm{x}=$. . . . . . . . . .
$(1)$ standard Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{C}_6 \mathrm{H}_6(1)$, for the reaction $6 \mathrm{C}$ (graphite) $+3 \mathrm{H}_2(\mathrm{~g}) \rightarrow \mathrm{C}_6 \mathrm{H}_n(1)$ is $48.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
$(2)$ Standard Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{CO}_2(\mathrm{~g})$, for the reaction $\mathrm{C}$ (graphite) $+\mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{CO}_2(\mathrm{~g})$ is $-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
$(3)$ Standard and Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{H}_2 \mathrm{O}(1)$, for the reaction $\mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{H}_2 \mathrm{O}(1)$ is $-286 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
$\begin{array}{*{20}{c}}
{\,\,\,C{H_3}{\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \\
{\,\,|{\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \\
{C{H_3} - CH - C{H_2} - O - C{H_2} - C{H_3} + HI\xrightarrow{{Heated}}{\mkern 1mu} ..........}
\end{array}$
Which of the following compounds will be formed ?