MCQ
For $d-$ block elements the first ionization potential is of the order
- ✓$Zn > Fe > Cu > Cr$
- B$Sc = Ti < V = Cr$
- C$Zn < Cu < Ni < Co$
- D$V > Cr > Mn > Fe$
$Zn\,:\,1{s^2}\,2{s^2}\,{p^6}\,3{s^2}\,{p^6}\,{d^{10}}\,4{s^2}$
$Fe\,:\,1{s^2}\,2{s^2}\,{p^6}\,3{s^2}\,{p^6}\,{d^6}\,4{s^2}$
$Cu\,:\,1{s^2}\,2{s^2}\,{p^6}\,3{s^2}\,{p^6}\,{d^{10}}\,4{s^1}$
$Cr\,:\,1{s^2}\,2{s^2}\,{p^6}\,3{s^2}\,{p^6}\,{d^5}\,4{s^1}$
$IE_1$ follows the order $:\,Zn > Fe > Cu > Cr$
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$r = P{Z_{AB}}{e^{ - Ea/RT}}$
which term is called steric factor

| Rate $mol\,L^{-1}\,s^{-1}$ | $[A]$ $mol\,L^{-1}$ | $[B]$ $mol\,L^{-1}$ |
| $0.10$ | $20$ | $0.5$ |
| $0.40$ | $x$ | $0.5$ |
| $0.80$ | $40$ | $y$ |
What is the value of $x$ and $y ?$