- AIn alkylation, a poisonous gas is evolved
- BIn alkylation, large amount of heat is evolved
- ✓In alkylation, pollyalkylated product is formed
- DAlkylation is very costly
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(Round off to the NearestInteger)
[Use:Atomicmasses:$Na:23.0\,u \mathrm{O}: 16.0 \,\mathrm{u} \quad \mathrm{H}: 1.0 \,\mathrm{u}$, Density of $\mathrm{H}_{2} \mathrm{O}: 1.0 \,\mathrm{~g} \,\mathrm{~cm}^{-3}$ ]
$\begin{array}{*{20}{c}}{ - OAc}\\{\rm{I}}\end{array}$$\begin{array}{*{20}{c}}{ - OMe}\\{{\rm{II}}}\end{array}$$\begin{array}{*{20}{c}}{ - OS{O_2}Me}\\{{\rm{III}}}\end{array}$$\begin{array}{*{20}{c}}{ - OS{O_2}C{F_3}}\\{{\rm{IV}}}\end{array}$
The order of leaving group ability is
$3 HC \equiv CH _{( g )} \rightleftharpoons C _{6} H _{6(\ell)}$
[Given: $\Delta_{f} G ^{\circ}( HC \equiv CH )=-2.04 \times 10^{5}\, J mol ^{-1}$
$\Delta_{f} G ^{\circ}\left( C _{6} H _{6}\right)=-1.24 \times 10^{5}\, J mol ^{-1} ; R =8.314\,\left. J K ^{-1} mol ^{-1}\right]$