Answer

(d): Urea does not dissociate into ions, thus, its van't Hoff factor is 1 . Whereas, all others furnish ions.
$ \begin{aligned} & \mathrm{AlCl}_3 \longrightarrow \mathrm{Al}^{3+}+3 \mathrm{Cl}^{-} ; i=4 \\ & \mathrm{~K}_2 \mathrm{SO}_4 \longrightarrow 2 \mathrm{~K}^{+}+\mathrm{SO}_4^{2-} ; i=3 \\ & \mathrm{NH}_4 \mathrm{Cl} \longrightarrow \mathrm{NH}_4^{+}+\mathrm{Cl}^{-} ; i=2 \end{aligned} $

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