- AMarkowikoff’s
- BBayer
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- DWurtz
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$2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{O}_{2}+4 \mathrm{H}^{\oplus}+4 \mathrm{e}^{-} ; \mathrm{E}_{\mathrm{red}}^{0}=1.23 \mathrm{V}$
$(\mathrm{R}=8.314 \;\mathrm{J} \mathrm{mol}^{-1} \mathrm{K}^{-1} ; \text { Temperature }=298 \;\mathrm{K} ;$ oxygen under std. atm. pressure of $1 \;bar$)
$\begin{array}{*{20}{c}}
{C{H_3} - CH - COOH} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{OH\,\,\,\,\,\,\,\,\,}
\end{array}\xrightarrow{\Delta }[Y]$
$[Y]$ will be :


$t/s$ $0$ $30$ $60$ $90$
$Ester/mol\, L^{-1}$ $0.55$ $0.31$ $0.17$ $0.085$
What will be the average rate of reaction between the time interval $30$ to $60$ seconds?