STD 12 - 6. Haloalkanes and Haloarenes — NEET STD 11 Science — Question

(consider complete conversion)

$\mathrm{I}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{I}\ \ \   \mathrm{E}^{\circ}=0.54 $

$\mathrm{Cl}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cl}^{-} \ \ \  \mathrm{E}^{\circ}=1.36 $

$\mathrm{Mn}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Mn}^{2+} \ \ \  \mathrm{E}^{\circ}=1.50 $

$\mathrm{Fe}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Fe}^{2+} \ \ \  \mathrm{E}^{\circ}=0.77 $

$\mathrm{O}_2+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_2 \mathrm{O} \ \ \  \mathrm{E}^{\circ}=1.23$

$1.$ Among the following, identify the correct statement.

$(A)$ Chloride ion is oxidized by $\mathrm{O}_2$

$(B)$ $\mathrm{Fe}^{2+}$ is oxidized by iodine

$(C)$ Iodide ion is oxidized by chlorine

$(D)$ $\mathrm{Mn}^{2+}$ is oxidized by chlorine

$2.$ While $\mathrm{Fe}^{3+}$ is stable, $\mathrm{Mn}^{3+}$ is not stable in acid solution because

$(A)$ $\mathrm{O}_2$ oxidises $\mathrm{Mn}^{2+}$ to $\mathrm{Mn}^{3+}$

$(B)$ $\mathrm{O}_2$ oxidises both $\mathrm{Mn}^{2+}$ and $\mathrm{Fe}^{2+}$ to $\mathrm{Fe}^{3+}$

$(C)$ $\mathrm{Fe}^{3+}$ oxidizes $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$(D)$ $\mathrm{Mn}^{3+}$ oxidises $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$3.$ Sodium fusion extract, obtained from aniline, on treatment with iron $(II)$ sulphate and $\mathrm{H}_2 \mathrm{SO}_4$ in presence of air gives a Prussian blue precipitate. The blue colour is due to the formation of

$(A)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(B)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$

$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$ $(D)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$

Give the answer question $1,2$ and $3.$