MCQ
Freundlich adsorption isotherm is given by the expression $\frac{\text{x}}{\text{m}}=\text{k}\ \text{p}^\frac{1}{\text{n}}$ which of the following conclusions can be drawn from this expression.
$a.$ When $\frac{1}{\text{n}}=0,$ the adsorption is independent of pressure.
$b.$ When $\frac{1}{\text{n}}=0,$ the adsorption is directly proportional to pressure.
$c.$ When $\text{n}=0,\ \frac{\text{x}}{\text{m}}\ vs\ p$ graph is a line parallel to $x-$axis.
$d.$ When $\text{n}=0,$ plot of $\frac{\text{x}}{\text{m}}\ vs\ p$ is a curve.
  • $a$ and $c$
  • B
    $a$ and $b$
  • C
    $b$ and $d$
  • D
    $a$ and $d$

Answer

Correct option: A.
$a$ and $c$
$(\text{a},\text{c})\frac{\text{x}}{\text{m}}=\text{k}\ \text{p}^\frac{1}{\text{n}}$
Whan $\frac{1}{\text{n}}=0,\ \frac{\text{x}}{\text{m}}=$ constant, the adsorption is indendent of the pressure.
When $\text{n}=0,\frac{\text{x}}{\text{m}}$ versus $p$ graph is a line parallel to $x-$axis

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