Question
Give following conversion in three steps:
Ethanoic acid into Methanol

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Calculate e.m.f of the following cell at 298 K:
2Cr(s)+3Fe2+(0.1M) $\rightarrow$ 2Cr3+(0.01M)+3Fe(s)
Given: E°(Cr3+|Cr)= –0.74 V E°(Fe2+|Fe) = –0.44 V
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
Experiment [A]/mol L-1 [B]/mol L-1 Initial rate/mol L-1 min-1
I 0.1 0.1 2.0 × 10-2
II - 0.2 4.0 × 10-2
III 0.4 0.4 -
IV - 0.2 2.0 × 10-2
  1. Define crystal field splitting energy. On the basis of crystal field theory, write the electronic configuration for d4 ion if $\triangle_0$< P.
  2. [Ni(CN)4]2– is colourless whereas [Ni(H2O)6]2+ is green. Why? (At. no. of Ni = 28)
Answer the following questions:
Give reasons:
  1. Among transition metals, the highest oxidation state is exhibited in oxoanions of a metal.
  2. Ce4+ is used as an oxidising agent in volumetric analysis.
  3. Zn2+ salts are white while Cu2+ salts are blue.
Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol.
Write chemical equations for the following reactions:
  1. Propanone is treated with dilute Ba(OH)2.
  2. Acetophenone is treated with Zn(Hg)/ Conc. HCl
  3. Benzoyl chloride is hydrogenated in presence of Pd/ BaSO4.
Describe for any two of the following complex ions, the type of hybridization, shape and magnetic property:
  1. [Fe(H2O6)]2+
  2. [Co(NH3)6]3+
  3. [NiCl4]2-
(At. Nos. Fe = 26, Co = 27, Ni = 28).
The rate constant for the first order decomposition of H2O2 is given by the following equation:

$\log{k}=14.2-\frac{\text{1.0}\times\text{10}^{4}}{\text{T}}K$

Calculate Ea for this reaction and rate constant k if its half-life period be 200 minutes.
(Given: R = 8.314 J K–1 mol–1)

  1. Urea forms an ideal solution in water. Determine the vapour pressure of anaqueous solution containing 10% by mass of urea at 40°C. (Vapour pressure of water at 40°C = 55.3 mm of Hg)
  2. Why is freezing point depression of 0.1 M sodium chloride solution nearly twice that of 0.1 M glucose solution?
Predict the order of reactivity of the following compounds in SN1 and SN2 reactions:
C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5)Br.