Question
Give reasons:
Physisorption decrease with increase of temperature.

Answer

As physisorption is an exothermic process:
$\text{Solid}\ \ \ \ +\ \ \ \ \text{Gas}\ \ \ \ \ \rightarrow\ \ \ \ \text{Gas }/\text{Solid}\ \ \ \ +\ \ \ \ \text{Heat}\\^\text{(Adsorbent)}\ \ \ \ \ ^\text{(Absorbate)}\ \ \ \ \ ^\text{(Gas absorbed on solid)}$
According to Le Chatelier’s principle, if we increase the temperature, equilibrium will shift in the backward direction, i.e., gas is released from the adsorbed surface.

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