Given below are two statements: Statement I : Aniline is less bas… - Vidyadip

MCQ

Given below are two statements:

Statement $I :$ Aniline is less basic than acetamide.

Statement $II :$ In aniline, the lone pair of electrons on nitrogen atom is delocalised over benzene ring due to resonance and hence less available to a proton.

Choose the most appropriate option:

A
Both statement $I$ and statement $II$ are true.
B
Both statement $I$ and statement $II$ are false.
C
Statement $\mathrm{I}$ is true but statement $II$ is false.
✓
Statement $\mathrm{I}$ is false but statement $II$ is true.

✓

Answer

Correct option: D.

Statement $\mathrm{I}$ is false but statement $II$ is true.

d
Explanation :- aniline is more basic than acetamide because in acetamide, lone pair of nitrogen is delocalized to more electronegative element oxygen.

In Aniline lone pair of nitrogen delocalised over benzene ring.

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