Given below are two statements:

Statements$-I :$ In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom.

Statement$-II :$ The group is migrated in Hofmann degradation reaction to electron deficient atom.

In the light of the above statement, choose the most appropriate answer from the options given below

Q: Given below are two statements: Statements$-I :$ In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom. Statement$-II :$ The group is migrated in Hofmann degradation reaction to electron deficient atom. In the light of the above statement, choose the most appropriate answer from the options given below

d $R - CO - NH _{2}+ Br _{2}+ NaOH \rightarrow$ $R - NH _{2}+ Na _{2} CO _{3}+ NaBr + H _{2} O$ $R - CO - NH _{2}+\overline{ O }H \rightarrow R - CO -\overline{ N }H \stackrel{ Br _{2}}{\longrightarrow}$ $R - CO - NH - Br \stackrel{ OH ^{-}}{\longrightarrow} R - CO -\overline{ N }- Br$ $\stackrel{\text { migration of } \overline{ R }}{\longrightarrow} R - NCO \stackrel{2 \overline{O}H}{\longrightarrow} RNH _{2}+ CO _{3}^{2-}$ In this reaction of alkyl as well as aryl group can migrate to electron deficient nitrogen atom.

Question

Given below are two statements:

Statements$-I :$ In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom.

Statement$-II :$ The group is migrated in Hofmann degradation reaction to electron deficient atom.

In the light of the above statement, choose the most appropriate answer from the options given below

ABoth Statement$-I$ and Statement$-II$ are correct
BBoth Statement$-I$ and Statement$-II$ are incorrect
CStatement$-I$ is correct but Statement$-II$ is incorrect
DStatement$-I$ is incorrect but Statement$-II$ is correct

JEE MAIN 2022, Difficult

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