Question
How do the oxides of transition elements in lower oxidation states differ from those in higher oxidation state in the nature of metal-oxygen bonding and why?

Answer

In the lower oxidation state the transition metal oxides are basic and they are acidic if the metal is in higher oxidation state. The oxides are amphoteric when the metal is in intermediate oxidation state. For example.
+3 +4 +7
Mn2O3 MnO2 Mn2O7
Basic Amphoteric Acidic

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